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In chemistry, metal-catalysed hydroboration is a reaction used in organic synthesis. It is one of several examples of homogeneous catalysis. ==History== In 1975, Kono and Ito reported that Wilkinson's catalyst (Rh(PPh3)3Cl) can undergo oxidative addition with catecholborane (HBcat) or 4,4,6-trimethyl-1,3,2-dioxaborinane. These two borane compounds are otherwise slow to participate in hydroboration. In 1985, Männig and Nöth demonstrated for the first time that Wilkinson’s catalyst indeed catalyzes hydroboration of alkenes with HBcat. : Whereas uncatalyzed hydroboration using HBcat leads to reduction of the carbonyl group, the catalyzed version is selective for the alkene. : As indicated by subsequent research, transition metal-catalyzed hydroboration proceeds with attractive functional group-, regio-, stereo-, and chemo- selectivity. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Metal-catalysed hydroboration」の詳細全文を読む スポンサード リンク
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